Structure and formation method of semiconductor device structure with gate stack

ABSTRACT

Structures and formation methods of a semiconductor device structure are provided. The semiconductor device structure includes a semiconductor substrate and a gate electrode over the semiconductor substrate. The semiconductor device structure also includes a source/drain structure adjacent to the gate electrode. The semiconductor device structure further includes a spacer element over a sidewall of the gate electrode, and the spacer element has an upper portion having a first exterior surface and a lower portion having a second exterior surface. Lateral distances between the first exterior surface and the sidewall of the gate electrode are substantially the same. Lateral distances between the second exterior surface and the sidewall of the gate electrode increase along a direction from a top of the lower portion towards the semiconductor substrate.

PRIORITY CLAIM AND CROSS-REFERENCE

This Application claims the benefit of U.S. Provisional Application No. 62/096,745, filed on Dec. 24, 2014, the entirety of which is incorporated by reference herein.

BACKGROUND

The semiconductor integrated circuit (IC) industry has experienced rapid growth. Technological advances in IC materials and design have produced generations of ICs. Each generation has smaller and more complex circuits than the previous generation.

In the course of IC evolution, functional density (i.e., the number of interconnected devices per chip area) has generally increased while geometric size (i.e., the smallest component (or line) that can be created using a fabrication process) has decreased. This scaling down process generally provides benefits by increasing production efficiency and lowering associated costs. However, these advances have increased the complexity of processing and manufacturing ICs.

Since feature sizes continue to decrease, fabrication processes continue to become more difficult to perform. Therefore, it is a challenge to form reliable semiconductor devices at smaller and smaller sizes.

BRIEF DESCRIPTION OF THE DRAWINGS

Aspects of the present disclosure are best understood from the following detailed description when read with the accompanying figures. It should be noted that, in accordance with the standard practice in the industry, various features are not drawn to scale. In fact, the dimensions of the various features may be arbitrarily increased or reduced for clarity of discussion.

FIGS. 1A-1I are cross-sectional views of various stages of a process for forming a semiconductor device structure, in accordance with some embodiments.

DETAILED DESCRIPTION

The following disclosure provides many different embodiments, or examples, for implementing different features of the provided subject matter. Specific examples of components and arrangements are described below to simplify the present disclosure. These are, of course, merely examples and are not intended to be limiting. For example, the formation of a first feature over or on a second feature in the description that follows may include embodiments in which the first and second features are formed in direct contact, and may also include embodiments in which additional features may be formed between the first and second features, such that the first and second features may not be in direct contact. In addition, the present disclosure may repeat reference numerals and/or letters in the various examples. This repetition is for the purpose of simplicity and clarity and does not in itself dictate a relationship between the various embodiments and/or configurations discussed.

Further, spatially relative terms, such as “beneath,” “below,” “lower,” “above,” “upper” and the like, may be used herein for ease of description to describe one element or feature's relationship to another element(s) or feature(s) as illustrated in the figures. The spatially relative terms are intended to encompass different orientations of the device in use or operation in addition to the orientation depicted in the figures. The apparatus may be otherwise oriented (rotated 90 degrees or at other orientations) and the spatially relative descriptors used herein may likewise be interpreted accordingly.

Some embodiments of the disclosure are described. FIGS. 1A-1I are cross-sectional views of various stages of a process for forming a semiconductor device structure, in accordance with some embodiments. Additional operations can be provided before, during, and/or after the stages described in FIGS. 1A-1I. Some of the stages that are described can be replaced or eliminated for different embodiments. Additional features can be added in the semiconductor device structure. Some of the features described below can be replaced or eliminated for different embodiments.

As shown in FIG. 1A, a semiconductor substrate 100 is provided. In some embodiments, the semiconductor substrate 100 is a bulk semiconductor substrate, such as a semiconductor wafer. For example, the semiconductor substrate 100 is a silicon wafer. The semiconductor substrate 100 may include silicon or other elementary semiconductor materials such as germanium. In some other embodiments, the semiconductor substrate 100 includes a compound semiconductor. The compound semiconductor may include gallium arsenide, silicon carbide, indium arsenide, indium phosphide, another suitable compound semiconductor, or a combination thereof. In some embodiments, the semiconductor substrate 100 includes a semiconductor-on-insulator (SOI) substrate. The SOI substrate may be fabricated using a separation by implantation of oxygen (SIMOX) process, a wafer bonding process, another applicable method, or a combination thereof.

In some embodiments, isolation features (not shown) are formed in the semiconductor substrate 100 to define and isolate various device elements (not shown) formed in the semiconductor substrate 100. The isolation features include, for example, shallow trench isolation (STI) features or local oxidation of semiconductor (LOCOS) features.

Examples of the various device elements that may be formed in the semiconductor substrate 100 include transistors, diodes, another suitable element, or a combination thereof. The transistors may include metal oxide semiconductor field effect transistors (MOSFET), complementary metal oxide semiconductor (CMOS) transistors, bipolar junction transistors (BJT), high voltage transistors, high-frequency transistors, p-channel and/or n-channel field effect transistors (PFETs/NFETs). Various processes may be performed to form the various device elements. The processes include, for example, deposition, photolithography, etching, implantation, annealing, planarization, another applicable process, or a combination thereof.

As shown in FIG. 1A, a number of gate stacks including gate stacks 108A and 108B are formed over the semiconductor substrate 100, in accordance with some embodiments. In some embodiments, each of the gate stacks 108A and 108B includes a gate dielectric layer 102 and a gate electrode 104. In some embodiments, each of the gate stacks 108A and 108B includes a hard mask 106. The hard mask 106 is used to assist in the formation of the gate stacks 108A and 108B. In some embodiments, the hard mask 106 is made of silicon oxide, silicon nitride, silicon oxynitride, silicon carbide, silicon carbon nitride, another suitable material, or a combination thereof. In some embodiments, the hard mask 106 has a multi-layer structure. There are recesses 200 between the gate stacks, as shown in FIG. 1A. In some embodiments, the recesses 200 are trenches. Since feature sizes continue to decrease, the width of each of the recesses 200 is getting smaller and smaller.

In some embodiments, the gate dielectric layer 102 is made of silicon oxide, silicon nitride, silicon oxynitride, dielectric material with high dielectric constant (high-K), another suitable dielectric material, or a combination thereof. Examples of high-K dielectric materials include hafnium oxide, zirconium oxide, aluminum oxide, hafnium dioxide-alumina alloy, hafnium silicon oxide, hafnium silicon oxynitride, hafnium tantalum oxide, hafnium titanium oxide, hafnium zirconium oxide, another suitable high-K material, or a combination thereof. In some embodiments, the gate dielectric layer 102 is a dummy gate dielectric layer which will be removed in a subsequent process. The dummy gate dielectric layer is, for example, a silicon oxide layer.

In some embodiments, the gate electrode 104 includes polysilicon, a metal material, another suitable conductive material, or a combination thereof. In some embodiments, the gate electrode 104 is a dummy gate electrode layer and will be replaced with another conductive material such as a metal material. The dummy gate electrode layer is made of, for example, polysilicon.

In some embodiments, a gate dielectric material and a gate electrode layer are deposited over the semiconductor substrate 100. In some embodiments, the gate dielectric material and the gate electrode layer are sequentially deposited by using suitable deposition methods. The suitable deposition methods may include a chemical vapor deposition (CVD) process, an atomic layer deposition (ALD) process, a thermal oxidation process, a physical vapor deposition (PVD) process, another applicable process, or a combination thereof. Afterwards, with the assistance of the hard mask 106, the gate dielectric material and the gate electrode layer are patterned to form the gate stacks including the gate stacks 108A and 108B. In some embodiments, an interfacial layer is formed between the gate dielectric layer and the semiconductor substrate.

Afterwards, sealing elements 110 are formed over sidewalls of the gate stack 108A and 108B, as shown in FIG. 1A in accordance with some embodiments. In some embodiments, the sealing elements 110 are in direct contact with sidewalls 105 of the gate electrodes 104. The sealing elements 110 may be used to protect the gate electrodes 104 from damage while subsequent process operations are performed. The sealing elements 110 may also be used as a mask during a subsequent ion implantation operation.

In some embodiments, the sealing elements 110 are made of a dielectric material. The dielectric material may include silicon oxide, silicon oxynitride, silicon nitride, another suitable material, or a combination thereof. In some embodiments, a sealing material layer is deposited over the gate stacks 108A and 108B and the semiconductor substrate 100. The sealing material layer may be deposited using a CVD process, an ALD process, an oxidation process, a spin-on process, another applicable process, or a combination thereof. Afterwards, an etching process, such as a dry etching process, is performed to partially remove the sealing material layer. The remaining portions of the sealing material layer on the opposite sidewalls of the gate stacks 108A and 108B form the sealing elements 110, as shown in FIG. 1A.

In some embodiments, one or more ion implantation operations are performed to form light doped source and drain (LDS/D) regions (not shown) on opposite sides of the gate stacks 108A and 108B in the semiconductor substrate 100. Many variations and/or modifications can be made to embodiments of the disclosure. In some embodiments, the LDS/D regions are not formed. In some embodiments, the sealing elements 110 are not formed.

As shown in FIG. 1B, spacer elements 112 are formed over the sealing elements 110, in accordance with some embodiments. The spacer elements 112 may be used to protect the gate electrodes 104 from damage during subsequent process operations. The spacer elements 112 may also be used as a mask during a subsequent ion implantation operation. In some embodiments, each of the spacer elements 112 includes multiple sub-layers. These sub-layers may be made of the same material. Alternatively, some of the sub-layers may be made of different materials.

In some embodiments, the spacer elements 112 are made of a dielectric material. The dielectric material may include silicon nitride, silicon oxynitride, silicon oxide, another suitable material, or a combination thereof. In some embodiments, a spacer material layer is deposited over the gate stacks 108A and 108B, the sealing elements 110, and the semiconductor substrate 100. The spacer material layer may be deposited using a CVD process, an ALD process, a spin-on process, another applicable process, or a combination thereof. Afterwards, an etching process, such as a dry etching process, is performed to partially remove the spacer material layer. The remaining portions of the spacer material layer on the sealing elements 110 form the spacer elements 112, as shown in FIG. 1B.

As shown in FIG. 1C, one or more ion implantation operations 113 are performed to form doped regions 114 in the semiconductor substrate 100, in accordance with some embodiments. The doped regions 114 may allow a subsequent recess formation process to be performed more easily. In some embodiments, dopants including arsenic (As) and/or another suitable dopant are implanted into the semiconductor substrate 100 to form the doped regions 114. The gate stacks 108A and 108B and the spacer elements 112 together serve as an implantation mask during the implantation process for forming the doped regions 114.

Many variations and/or modifications can be made to embodiments of the disclosure. In some embodiments, the doped regions 114 are not formed. In some other embodiments, both the doped regions 114 and the spacer elements 112 are not formed. In some other embodiments, the doped regions 114 are not formed, and the spacer elements 112 are formed.

As shown in FIG. 1D, a spacer layer 116 is deposited over the semiconductor substrate 100, the spacer elements 112, and the gate stacks 108A and 108B, in accordance with some embodiments. In some embodiments, the spacer layer 116 is made of a dielectric material. The dielectric material may include silicon nitride, silicon oxynitride, silicon carbide, silicon carbon nitride, silicon oxide, another suitable material, or a combination thereof. In some embodiments, the spacer layer 116 is deposited using a CVD process, an ALD process, a spin-on process, another applicable process, or a combination thereof.

As shown in FIG. 1D, a protection material 115 is formed over the portions of the spacer layer 116 on bottoms of the recesses 200, in accordance with some embodiments. The protection material 115 may be used to control a subsequent patterning process of the spacer layer 116. In some embodiments, the protection material 115 is made of a carbon-containing layer. In some embodiments, the protection layer 115 is a remaining portion of an anti-reflection coating layer that is previously formed over the structure shown in FIG. 1D.

In some embodiments, an anti-reflection coating layer (a backside anti-reflection coating, BARC) and a patterned photoresist layer are formed over the semiconductor substrate 100 and the gate stacks. The patterned photoresist layer has one or more openings that expose the portions where subsequent processes will be performed. The other portions covered by the patterned photoresist layer are therefore protected. For example, the portions where n-type doped regions will be formed are covered, and the portions where p-type doped regions will be formed are not covered by the patterned photoresist layer. The anti-reflection coating layer under the photoresist layer may be used to assist in the photolithography process for patterning the photoresist layer. The anti-reflection coating layer may be a carbon-containing layer, such as a polymer layer or an inorganic layer that contains carbon.

In some embodiments, an etching process is performed afterwards to remove the portions of the anti-reflection coating layer exposed by the openings of the patterned photoresist layer. Therefore, subsequent processes can be performed on the exposed portions after the anti-reflection coating layer is partially removed. In some embodiments, the etching process is a plasma etching process which involves exciting a gas mixture to generate plasma for etching. In some embodiments, the gas mixture includes oxygen gas and hydrogen bromide gas. In some embodiments, the amount of the hydrogen bromide gas is modified such that the etching rate of the anti-reflection coating layer is retarded. For example, the amount of hydrogen bromide gas may be increased. As a result, after the etching process, the remaining portions of the anti-reflection coating layer on the bottoms of the recesses 200 form the protection material 115, as shown in FIG. 1D in accordance with some embodiments.

However, it should be appreciated that many variations and/or modifications can be made to embodiments of the disclosure. The formation method of the protection material 115 is not limited to the above-mentioned methods. In some other embodiments, the protection layer 115 is directly formed over the bottoms of the recesses 200 using a CVD process, a spin-on process, another applicable process, or a combination thereof. The protection material 115 is not limited to a carbon-containing material. In some other embodiments, the protection material 115 is made of silicon oxide, silicon oxynitride, silicon carbide, silicon carbon nitride, silicon nitride, another suitable material, or a combination thereof.

Afterwards, an etching process is performed to partially remove the spacer layer 116, as shown in FIG. 1E in accordance with some embodiments. The remaining portions of the spacer layer 116 over the spacer elements 112 form the spacer elements 116′, as shown in FIG. 1E. Each of the spacer elements 116′ includes an upper portion 117U and a lower portion 117L. In some embodiments, due to the protection material 115, the etching rate of the portions of the spacer layer 116 near the bottoms of the recesses 200 between the gate stacks is retarded. More material is remaining near the bottom of the recesses 200 such that the lower portion 117L has a protruding footing feature 202 and is wider than the upper portion 117U. The protection material 115 may be removed while the spacer layer 116 is etched to form the spacer elements 116′.

However, it should be appreciated that many variations and/or modifications can be made to embodiments of the disclosure. In some other embodiments, the protection material 115 is not formed. In some embodiments, the conditions of the etching process are fine-tuned such that the spacer elements 116′ having the desired profile such as that shown in FIG. 1E are formed. For example, the compositions of the etchants are tuned.

As shown in FIG. 1E, the upper portion 117U and the lower portion 117L have an exterior surface 119 a and an exterior surface 119 b, respectively. In some embodiments, the exterior surface 119 b of the lower portion 117L connects to the exterior surface 119 a of the upper portion 117U. In some embodiments, the exterior surface 119 a of the upper portion 117U is substantially parallel to the sidewall 105 of the gate electrode 104. In some embodiments, lateral distances between the exterior surface 119 a of the upper portion 117U and the sidewall 105 of the gate electrode 104 are substantially the same. For example, the lateral distances are substantially equal to the distance D₁, as shown in FIG. 1E. In some embodiments, the distance D₁ is a maximum lateral distance between the upper portion 117U of the spacer elements 116′ and the sidewall 105 of the gate electrode 104. In some embodiments, the distance D₁ is in a range from about 1 nm to about 20 nm. In some other embodiments, the distance D₁ is in a range from about 2 nm to about 10 nm.

In some embodiments, the exterior surface 119 b of the lower portion 117L is a curved surface. In some embodiments, the exterior surface 119 b curves inward, as shown in FIG. 1E. In some embodiments, lateral distances between the exterior surface 119 b of the lower portion 117L of the spacer element 116′ and the sidewall 105 of the gate electrode 104 increase along a direction from the top of the lower portion 117L towards the semiconductor substrate 100. In some embodiments, the lateral distances between the exterior surface 119 b of the lower portion 117L and the sidewall 105 gradually increase along the direction from the top of the lower portion 117L towards the semiconductor substrate 100. For example, the lateral distances gradually increase from the distance D₂ to the distance D₃, as shown in FIG. 1E. In some embodiments, the distance D₂ is equal to the distance D₁. In some embodiments, the distance D₂ is a lateral distance between a top of the lower portion 117L of the spacer elements 116′ and the sidewall 105 of the gate electrode 104. In some embodiments, the distance D₃ is a lateral distance between a bottom of the lower portion 117L of the spacer elements 116′ and the sidewall 105 of the gate electrode 104. In some embodiments, the distance D₂ is in a range from about 1 nm to about 20 nm. In some other embodiments, the distance D₂ is in a range from about 2 nm to about 10 nm. In some embodiments, the distance D₃ is in a range from about 2 nm to about 30 nm. In some embodiments, the distance D₃ is in a range from about 5 nm to about 15 nm.

In some embodiments, a ratio of one of the lateral distances between the exterior surface 119 b and the sidewall 105 to a lateral distance between the exterior surface 119 a and the sidewall 105 is in a range from about 1.2 to about 2. In some embodiments, the ratio of the distance D₃ to the distance D₁ is in a range from about 1.2 to about 2.

In some embodiments, the thicknesses of the upper portion 117U are substantially the same, as shown in FIG. 1E. For example, the upper portion 117U of the spacer element 116′ has a thickness t₁. In some embodiments, the thickness of the lower portion 117L of the spacer element 116′ is not uniform. In some embodiments, the thicknesses of the lower portion 117L increase along a direction from the top of the lower portion 117L towards the semiconductor substrate 100. In some embodiments, the thicknesses of the lower portion 117L gradually increase along a direction from the top of the lower portion 117L towards the semiconductor substrate 100. For example, the thickness gradually increases to a thickness t₃ from a thickness t₂. The thickness t₃ gradually increases to a thickness t₄, as shown in FIG. 1E in accordance with some embodiments. In some embodiments, the thickness t₄ is greater than the thickness t₁ by about 1 nm to about 3 nm. In some embodiments, the thickness t₃ is substantially equal to the average value of the thicknesses t₂ and t₄. In some embodiments, the thickness t₃ is the thickness of a middle portion of the lower portion 117L.

In some embodiments, the top of the lower portion 117L is as high as a height h of the gate electrode 104, and the height h is half of the total height H of the gate electrode 104. In some other embodiments, a ratio of the height h to the total height H of the gate electrode 104 (h/H) is in a range from about 1/8 to about 5/8. As shown in FIG. 1E, an angle θ is formed between the bottom of the spacer element 116′ (or the protruding footing feature 202) and the exterior surface 119 b. In some embodiments, the angle θ is in a range from about 1 degree to about 85 degrees. In some other embodiments, the angle θ is in a range from about 10 degrees to about 60 degrees.

As shown in FIG. 1E, after the spacer elements 116′ are formed, each of the recesses 200 now has a bottom width W₂ that is smaller than a top width W₁. The bottom width W₂ of the recess 200 is smaller because of the occupation of the lower portion 117L of the spacer element 116′. The protruding footing feature 202 covers a portion of the semiconductor substrate 100. Therefore, the bottom width W₂ of the recess 200 is smaller. A subsequent recess formation process may be well-controlled due to the protruding footing feature 202. Meanwhile, the top width W₁ of recess 200 remains large since the upper portion 117U of the spacer element 116′ does not occupy too much space of the recess 200. Therefore, a subsequent dielectric material filling process may still be performed smoothly.

As shown in FIG. 1F, a portion of the semiconductor substrate 100 is removed to form recesses 118, in accordance with some embodiments. In some embodiments, one or more etching processes are performed to form the recesses 118. The spacer elements 116′ may serve as an etching mask during the formation of the recesses 118. In some embodiments, the dopants in the doped regions 114 may react with the etchants in the etching processes. The profiles of the recesses 118 may therefore be controlled.

As shown in FIG. 1F, each of the recesses 118 laterally extends under the spacer element 116′. The region under the gate electrode 104 and between edges of the recesses 118 forms a channel region that has a channel length L. Because of the occupation of the lower portion 117L of the spacer element 116′ (or the protruding footing feature 202), the bottom width of the recess 200 is shrunk. Therefore, the lateral extending degrees of the recesses 118 are limited since some of the etchants are blocked by the protruding footing feature 202. As a result, the channel region may have a sufficient channel length L, which greatly improves the device performance. In some other cases where the spacer element does not have the protruding footing feature, the channel region may accordingly have a shorter length. The performance may not as good as that of the device structure in accordance with some embodiments of the disclosure.

As shown in FIG. 1G, source/drain structures 120 are formed in the recesses 118 and over the semiconductor substrate 100, in accordance with some embodiments. In some embodiments, the protruding footing features 202 of the spacer elements 116′ cover a portion of the source/drain structures 120, as shown in FIG. 1G. In some embodiments, the tops of the source/drain structures 120 are substantially coplanar with the top of the semiconductor substrate 100. However, embodiments of the disclosure are not limited thereto. In some other embodiments, the source/drain structures 120 are raised source/drain structures and protrude from the top of the semiconductor substrate 100. In some embodiments, the semiconductor substrate 100 shown in FIG. 1G is a fin structure. In these cases, the source/drain structures 120 serve as a source/drain region of a FinFET transistor.

In some embodiments, the source/drain structures 120 are formed using a selective epitaxial growth (SEG) process, a CVD process (e.g., a vapor-phase epitaxy (VPE) process, a low pressure chemical vapor deposition (LPCVD) process, and/or an ultra-high vacuum CVD (UHV-CVD) process), a molecular beam epitaxy process, another applicable process, or a combination thereof.

In some embodiments, the source/drain structures 120 are doped with one or more suitable dopants. For example, the source/drain structures 120 are SiGe source/drain features doped with boron (B) or another suitable dopant. Alternatively, in some other embodiments, the source/drain structures 120 are Si source/drain features doped with phosphor (P), antimony (Sb), or another suitable dopant.

In some embodiments, the source/drain structures 120 are doped in-situ during their epitaxial growth. In some other embodiments, the source/drain structures 120 are not doped during the growth of the source/drain structures 120. Instead, after the formation of the source/drain structures 120, the source/drain structures 120 are doped in a subsequent process. In some embodiments, the doping is achieved by using an ion implantation process, a plasma immersion ion implantation process, a gas and/or solid source diffusion process, another applicable process, or a combination thereof. In some embodiments, the source/drain structures 120 are further exposed to one or more annealing processes to activate the dopants. For example, a rapid thermal annealing process is used.

As shown in FIG. 1H, a dielectric layer 122 is formed over the spacer elements 116′, the gate stacks 108A and 108B, and the source/drain structures 120 to fill the recesses 200, in accordance with some embodiments. The dielectric layer 122 surrounds the spacer elements 116′ and the gate electrode 104. Because of the spacer element 116′ having the protruding footing feature 202, a channel region that has a sufficient length is obtained. As mentioned above, the top width W₁ of the recess 200 is still wide enough to allow a good filling of the dielectric layer 122. The upper portion 117L of the spacer element 116′ is thin enough such that the top width W₁ of the recess 200 is still wide enough. The filling of the dielectric layer 122 may therefore be performed more easily.

Afterwards, a polarization process is performed to thin the dielectric layer 122 until the gate electrodes 104 are exposed, as shown in FIG. 1H in accordance with some embodiments. The planarization process may include a chemical mechanical polishing (CMP) process, an etching process, a grinding process, another applicable process, or a combination thereof. In some embodiments, the hard mask 106 is also removed during the planarization process.

As mentioned above, the ratio of the distance D₃ to the distance D₁ is in a range from about 1.2 to about 2, in accordance with some embodiments. In some cases, if the ratio (D₃/D₁) is smaller than about 1.2, the distance D₃ may be too small. As a result, the channel length L may not be sufficient. Alternatively, the distance D₁ may be too long such that the filling of the dielectric layer 122 may be difficult to perform. In some other cases, if the ratio (D₃/D₁) is higher than about 2, the distance D₃ may be too long. As a result, the lateral extending degree of the recesses 118 may not be enough. The source/drain structure 120 may not be able to provide enough strain to increase the carrier mobility.

As shown in FIG. 1I, the gate dielectric layer 102 and the gate electrodes 104 are respectively replaced with a gate dielectric layer 124 and metal gate electrodes 130A and 130B, in accordance with some embodiments. In some embodiments, the gate electrode 104 and the dielectric layer 102 are removed sequentially using one or more etching processes to form recesses between the sealing elements 110.

Afterwards, the gate dielectric layer 102 is deposited over the dielectric layer 122 and the sidewalls and bottoms of the recesses between the sealing elements 110. In some embodiments, the gate dielectric layer 102 is a high-k dielectric layer. The high-k dielectric layer may be made of hafnium oxide, zirconium oxide, aluminum oxide, hafnium dioxide-alumina alloy, hafnium silicon oxide, hafnium silicon oxynitride, hafnium tantalum oxide, hafnium titanium oxide, hafnium zirconium oxide, another suitable high-K material, or a combination thereof. In some embodiments, the gate dielectric layer 124 is deposited using an ALD process or another applicable process. In some embodiments, a high temperature annealing operation is performed to reduce or eliminate defects in the gate dielectric layer 124.

In some other embodiments, before the gate dielectric layer 124 is formed, an interfacial layer (not shown) is formed in the recesses between the sealing elements 110. The interfacial layer may be used to reduce stress between the gate dielectric layer 124 and the semiconductor substrate 100. In some embodiments, the interfacial layer may be made of silicon oxide. In some embodiments, the interfacial layer is formed using an ALD process, a thermal oxidation process, another applicable process, or a combination thereof.

Afterwards, a work function layer 126 is deposited over the gate dielectric layer 124, as shown FIG. 1I in accordance with some embodiments. In some embodiments, the work function layer 126 includes multiple sub-layers. In some embodiments, these sub-layers are made of different materials. In some other embodiments, these sub-layers are made of the same material. The work function layer 126 is used to provide desired work function for transistors to enhance device performance including improved threshold voltage. In the embodiments of forming an NMOS transistor, the work function layer 126 can be an n-type metal layer capable of providing a work function value suitable for the device, such as equal to or less than about 4.5 eV. The n-type metal layer may include metal, metal carbide, metal nitride, or a combination thereof. For example, the n-type metal layer includes titanium nitride, tantalum, tantalum nitride, other suitable materials, or a combination thereof.

On the other hand, in the embodiments of forming a PMOS transistor, the work function layer 126 can be a p-type metal layer capable of providing a work function value suitable for the device, such as equal to or greater than about 4.8 eV. The p-type metal layer may include metal, metal carbide, metal nitride, other suitable materials, or a combination thereof. For example, the p-type metal includes tantalum nitride, tungsten nitride, titanium, titanium nitride, other suitable materials, or a combination thereof.

The work function layer 126 may also be made of hafnium, zirconium, titanium, tantalum, aluminum, metal carbides (e.g., hafnium carbide, zirconium carbide, titanium carbide, aluminum carbide), aluminides, ruthenium, palladium, platinum, cobalt, nickel, conductive metal oxides, or a combinations thereof. The thickness and/or the compositions of the work function layer 126 may be tuned to adjust the work function level. For example, a titanium nitride layer may be used as a p-type metal layer or an n-type metal layer, depending on the thickness and/or the compositions of the titanium nitride layer.

In some embodiments, a barrier layer (not shown) is deposited over the gate dielectric layer 124, before the work function layer 126 is deposited. The barrier layer may be used to interface the gate dielectric layer 124 with the work function layer 126. The barrier layer may also be used to prevent diffusion between the gate dielectric layer 124 and the work function layer 126. In some embodiments, the barrier layer is made of a metal-containing material. The metal-containing material may include titanium nitride, tantalum nitride, other suitable materials, or a combination thereof. In some embodiments, the barrier layer includes multiple layers. In some embodiments, the barrier layer is deposited using an ALD process, a physical vapor deposition (PVD) process, a plating process, other applicable processes, or a combination thereof. In some other embodiments, the barrier layer is not formed.

Afterwards, a metal filling layer 128 is deposited over the work function layer 126 to fill the recesses between the sealing elements 110, as shown in FIGS. 1I in accordance with some embodiments. In some embodiments, the metal filling layer 128 is made of aluminum, tungsten, copper, another suitable material, or a combination thereof. In some embodiments, the metal filling layer 128 is deposited using a PVD process, a plating process, a CVD process, another applicable process, or a combination thereof.

Afterwards, a planarization process is performed to remove the portions of the gate dielectric layer 124, the work function layer 126, and the metal filling layer 128 outside of the recesses between the sealing elements 110, as shown in FIG. 1I in accordance with some embodiments. The remaining portions of the work function layer 126 and the metal filling layer 128 together form the metal gate electrodes 130A and 130B, as shown in FIG. 1I. The planarization process may include a CMP process, a grinding process, an etching process, another applicable process, or a combination thereof.

Many variations and/or modifications can be made to embodiments of the disclosure. In some embodiments, the top of the spacer element 116 is as high as the tops of the metal gate electrode 130A and 130B, as shown in FIG. 1I. However, embodiments of the disclosure are not limited thereto. In some embodiments, the spacer element 116′ does not reach the top of the spacer element 112. In these cases, the spacer element 116′ is lower than the tops of the metal gate electrodes 130A and 130B.

Embodiments of the disclosure form spacer element that includes a protruding footing feature. Due to the protruding footing feature, the channel length under the gate electrode can be controlled according to requirements. The upper portion of the spacer element is thin and does not occupy too much space between gate stacks. Therefore, a subsequent deposition of a dielectric layer between the gate stacks can be performed smoothly. The reliability and performance of the device structure are improved significantly.

In accordance with some embodiments, a semiconductor device structure is provided. The semiconductor device structure includes a semiconductor substrate and a gate electrode over the semiconductor substrate. The semiconductor device structure also includes a source/drain structure adjacent to the gate electrode. The semiconductor device structure further includes a spacer element over a sidewall of the gate electrode, and the spacer element has an upper portion having a first exterior surface and a lower portion having a second exterior surface. Lateral distances between the first exterior surface and the sidewall of the gate electrode are substantially the same. Lateral distances between the second exterior surface and the sidewall of the gate electrode increase along a direction from a top of the lower portion towards the semiconductor substrate.

In accordance with some embodiments, a semiconductor device structure is provided. The semiconductor device structure includes a semiconductor substrate and a gate electrode over the semiconductor substrate. The semiconductor device structure also includes a source/drain structure over the semiconductor substrate and adjacent to the gate electrode. The semiconductor device structure further includes a spacer element over a sidewall of the gate electrode. The spacer element has a protruding footing feature, and the protruding footing feature covers a portion of the source/drain structure.

In accordance with some embodiments, a method for forming a semiconductor device structure is provided. The method includes forming a gate electrode over a semiconductor substrate and forming a spacer element over a sidewall of the gate electrode. The spacer element has a protruding footing feature. The method also includes forming a recess in the semiconductor substrate, and the recess extends laterally under the spacer element. The method further includes forming a source/drain structure in the recess.

The foregoing outlines features of several embodiments so that those skilled in the art may better understand the aspects of the present disclosure. Those skilled in the art should appreciate that they may readily use the present disclosure as a basis for designing or modifying other processes and structures for carrying out the same purposes and/or achieving the same advantages of the embodiments introduced herein. Those skilled in the art should also realize that such equivalent constructions do not depart from the spirit and scope of the present disclosure, and that they may make various changes, substitutions, and alterations herein without departing from the spirit and scope of the present disclosure. 

What is claimed is:
 1. A semiconductor device structure, comprising: a semiconductor substrate; a gate electrode over the semiconductor substrate; a source/drain structure adjacent to the gate electrode; and a spacer element over a sidewall of the gate electrode, wherein: the spacer element has an upper portion having a first exterior surface and a lower portion having a second exterior surface, lateral distances between the first exterior surface and the sidewall of the gate electrode are substantially the same, and lateral distances between the second exterior surface and the sidewall of the gate electrode increase along a direction from a top of the lower portion towards the semiconductor substrate.
 2. The semiconductor device structure as claimed in claim 1, wherein a ratio of one of the lateral distances between the second exterior surface and the sidewall of the gate electrode to a lateral distance between the first exterior surface and the sidewall of the gate electrode is in a range from about 1.2 to about
 2. 3. The semiconductor device structure as claimed in claim 1, wherein the second exterior surface comprises a curved surface.
 4. The semiconductor device structure as claimed in claim 3, wherein the curved surface of the second exterior surface curves inward.
 5. The semiconductor device structure as claimed in claim 1, wherein thicknesses of the lower portion of the spacer element gradually increase along a direction from a top of the lower portion of the spacer element towards the semiconductor substrate.
 6. The semiconductor device structure as claimed in claim 1, wherein thicknesses of the upper portion of the spacer element are substantially the same.
 7. The semiconductor device structure as claimed in claim 1, wherein the lower portion of the spacer element is wider than the upper portion of the spacer element.
 8. The semiconductor device structure as claimed in claim 1, further comprising a second spacer element between the spacer element and the gate electrode.
 9. The semiconductor device structure as claimed in claim 1, wherein an angle between a bottom of the spacer element and the second exterior surface is in a range from about 1 degree to about 85 degrees.
 10. The semiconductor device structure as claimed in claim 1, wherein the first exterior surface is substantially parallel to the sidewall of the gate electrode.
 11. A semiconductor device structure, comprising: a semiconductor substrate; a gate electrode over the semiconductor substrate; a source/drain structure adjacent to the gate electrode; and a spacer element over a sidewall of the gate electrode, wherein the spacer element has a protruding footing feature, and the protruding footing feature covers a portion of the source/drain structure.
 12. The semiconductor device structure as claimed in claim 11, wherein the protruding footing feature has a curved exterior surface.
 13. The semiconductor device structure as claimed in claim 12, wherein the curved exterior surface curves inward.
 14. The semiconductor device structure as claimed in claim 11, wherein thicknesses of the protruding footing feature gradually increases along a direction from a top of the protruding footing feature towards the semiconductor substrate.
 15. The semiconductor device structure as claimed in claim 11, wherein the spacer element has an upper portion over the protruding footing feature, and the upper portion has an exterior surface substantially parallel to a sidewall of the gate electrode.
 16. A method for forming a semiconductor device structure, comprising: forming a gate electrode over a semiconductor substrate; forming a spacer element over a sidewall of the gate electrode, wherein the spacer element has a protruding footing feature; forming a recess in the semiconductor substrate, wherein the recess extends laterally under the spacer element; and forming a source/drain structure in the recess.
 17. The method for forming a semiconductor device structure as claimed in claim 16, wherein the formation of the spacer element comprises: forming a spacer layer over the semiconductor substrate and the gate electrode; forming a protection material over a portion of the spacer layer over the semiconductor substrate; and partially etching the spacer layer, wherein a remaining portion of the spacer layer over the sidewall of the gate electrode forms the spacer element, wherein the protection material is removed during the etching of the spacer layer.
 18. The method for forming a semiconductor device structure as claimed in claim 16, further performing an ion implantation process on the semiconductor substrate before the spacer element is formed.
 19. The method for forming a semiconductor device structure as claimed in claim 16, further comprising forming a second spacer element over the sidewall of the gate electrode before the spacer element is formed.
 20. The method for forming a semiconductor device structure as claimed in claim 16, further comprising: forming a dielectric layer to surround the spacer element and the gate electrode; and replacing the gate electrode with a metal gate electrode. 